|
|
Measurement and Uncertainty Evaluation of Fullerene Purity Based on Ultraviolet-visible Spectrophotometer |
ZHAO Chun-yue1,2,RENG Ling-ling2,PU Cheng2,SHAO Hong-fei3,YAO Ya-xuan2 |
1. College of Chemical Engineering,Shenyang University of Chemical Technology,Shenyang, Liaoning 110142,China
2. Center for Advanced Measurement Science,National Institute of Metrology,Beijing 100029,China
3. Shandong Institute of Nonmetallic Materials, Jinan, Shandong 250031,China |
|
|
Abstract The purity has an impact on fullerene’s mechanical, thermal and other properties of fullerene, hence its applications in lubricity, superconductivity and other related areas. Ultraviolet-visible (UV-vis) spectrophotometer is a simple and convenient technique for rapid determination of fullerene purity. Yet, elaborated systematic analysis on measurement influencing factors are currently not been reported. Based on UV-vis spectrophotometer, a mathematical model for purity determination of C60 was established, and uncertainty was evaluated by analyzing all possible uncertainty sources. The results showed that the purity of C60 prepared by arc method is (74±7)%, k=2; and the purity of C60 prepared by combustion method is (99±9)%, k=2. Based on uncertainty evaluation, main sources of uncertainty come from linear fitting of standard curve and preparation of standard series solutions, which may provide technical basis for optimization of measurement conditions with reduced uncertainty and improved accuracy for future study.
|
Received: 08 September 2022
Published: 27 December 2023
|
|
|
|
|
[8] |
李积彬, 李瀚, 孙伟安. C_(60)的摩擦学特性研究[J]. 摩擦学学报, 2000,20(4): 307-309.
|
[1] |
黄飞, 徐慧敏, 黄成相, 等. 富勒烯C_(60)的性能及应用研究进展[J]. 五邑大学学报: 自然科学版, 2017, 31(1): 24-28.
|
[18] |
JJG 178—2007 紫外、可见、近红外分光光度计检定规程 [S].
|
|
Xie J. Fullerene development and application research [J]. Journal of Shandong Institute of Commerce and Technology, 2003 (4): 64-67.
|
[5] |
王静. (4, 6)-富勒烯结构和性质的理论研究 [D]. 太原: 山西大学, 2015.
|
[2] |
黄飞, 李长江, 兰艳素, 等. 富勒烯C_(60)纳米材料的制备及其应用研究进展[J]. 化工新型材料, 2015, 43(11): 7-9.
|
[3] |
Baskar A V, Benzigar M R, Talapaneni S N, et al. Self-Assembled Fullerene Nanostructures: Synthesis and Applications [J]. Advanced Functional Materials, 2021, 32(6), 2106924.
|
|
Wang H, Zong N, Chen Z Z, et al. Research Progress in Preparation and Purification of Fullerene[J]. Materials Reports, 2021, 35(S1): 71-77.
|
|
Miao L, Liu M. Current Situation of Fullerene Industry in China and Its Countermeasures[J]. Technological Development of Enterprise, 2019, 38(7): 5-10.
|
|
Li J B, Li H, Sun W A. Study of tribological properties of C_(60) [J]. Tribology, 2000,20(4): 307-309.
|
|
Shen H J, Mu X C. Compressive mechanical properties and electronic structure of C_(60), C_(180), C_(60)@C_(180) fullerene molecules[J]. Chinese Journal of Materials Research, 2006, 20(1): 93-98.
|
|
Si M L, Wang H F, Li Y F, et al. Preparation and performance characterization of flexible high thermal conductivity graphene/fullerene composite films[J]. Journal of Functional Material, 2020, 51(7): 7022-7026.
|
[11] |
Jovanovic′ T, Koruga D, Mitrovic′ A, et al. IR and UV/VIS Spectroscopic Characterization of the Higher Fullerene C76-D2 for Its Quantitative and Qualitative Determination [J]. Journal of Nanomaterials, 2018(3):1-9.
|
[14] |
洪名放, 邹汉法. C_(60), C_(70)液相色谱分离方法的研究[J]. 色谱, 1994(6): 424-425.
|
|
Chen W X. Absorption spectrum of C70[J]. Spectroscopy and Spectral Analysis, 1999, 19(2): 177-178.
|
|
Huang F, Xu H M, Huang C X, et al. Progress of Research on Properties of Fullerene C_(60) and Its Application [J]. Journal of Wuyi University (Natural Science Edition), 2017, 31(1): 24-28.
|
[6] |
王浩, 宗楠, 陈中正, 等. 富勒烯制备与提纯方法研究进展[J]. 材料导报, 2021, 35(S1): 71-77.
|
[7] |
苗蕾, 刘淼. 我国富勒烯产业发展现状分析及对策研究[J]. 企业技术开发, 2019, 38(7): 5-10.
|
[10] |
孙宝云, 崔荣丽. 一种富勒烯的定量分析方法[P]. 中国: CN 103743690 A, 2014.
|
[12] |
骆初平, 甘良兵, 周永芬, 等. 利用紫外-可见吸收光谱同时定量分析C_(60)和C_(70)[J]. 北京大学学报: 自然科学版, 1995, 31(4): 432-438.
|
[13] |
钟圆圆. 基于电弧放电法合成氯化富勒烯的分离与表征 [D]. 厦门: 厦门大学, 2018.
|
[15] |
Zhuo C, Westerhoff P, Herckes P. Quantification of C60 fullerene concentrations in water [J]. Environmental Toxicology & Chemistry, 2010, 27(9): 1852-1859.
|
|
GB/T 42241—2022 纳米技术[60]/[70]富勒烯的纯度的测定 高效液相色谱法[S].
|
[19] |
解菊. 富勒烯的发展及应用研究 [J]. 山东商业职业技术学院学报, 2003 (4): 64-67.
|
[20] |
陈万湘. C70的吸收光谱[J]. 光谱学与光谱分析, 1999, 19(2): 177-178.
|
[24] |
JJG 1036—2008 电子天平检定规程 [S].
|
[26] |
邸铮, 贾伯阳, 周荔, 等. 高效液相色谱法测定化妆品中防晒剂奥克立林含量的不确定度评定[J]. 计量学报, 2020, 41(12): 1570-1575.
|
[27] |
袁国文, 金文丽, 隆旭红, 等. 紫外-可见分光光度法测定盐酸雷尼替丁胶囊含量的不确定度评定[J]. 药物分析志, 2011, 31(3): 579-582.
|
[4] |
Pan Y, Liu X J, Zhang W, et al. Advances in photocatalysis based on fullerene C60 and its derivatives: Properties, mechanism, synthesis, and applications [J]. Applied Catalysis B: Environmental, 2020, 265(15): 118579.
|
[9] |
司马林, 王鹤峰, 李永锋, 等. 柔性高导热石墨烯/富勒烯复合薄膜的制备及性能表征[J]. 功能材料, 2020, 51(7): 7022-7026.
|
[16] |
Kuznetsov S I, Yunusova D S, Yumagulova R K, et al. Quantitative UV Spectrophotometric Analysis of Mixtures of Substituted C60 Fullerenes[J]. Journal of Applied Spectroscopy, 2015, 82(4): 644-652.
|
|
Zhang L y, He S Z, Qiu H R, et al. Uncertainty Evaluation for the Furfural Content in Transformer Oil by HPLC[J]. Acta Metrologica Sinica, 2022, 43(4): 560-564.
|
[22] |
CNAS-GL06: 2006 化学分析中不确定度的评估指南 [S].
|
|
Yuan G W, Jin W L, Long X H, et al. Evaluation of uncertainty measurement in content determination ranitidine hydrochloride capsules by UV spectrophotometry[J]. Chinese Journal of Pharmaceutical Analysis, 2011, 31(3): 579-582.
|
|
Huang F, Li C J, Lan S Y, et al. Reseach progress of perparation method and application of fullerene C_(60) nanomaterials[J]. New Chemical Materials, 2015, 43(11): 7-9.
|
[9] |
沈海军, 穆先才. C_(60), C_(180), C_(60)@C_(180)富勒烯分子的压缩力学特性与电子结构[J]. 材料研究学报, 2006, 20(1): 93-98.
|
|
Hong M F, Zou H F. Research on the separation method of C_(60), C_(70) by liquid chromatography[J]. Chinese Journal of Chromatography, 1994(6): 424-425.
|
[21] |
张琳颖, 贺石中, 丘晖饶, 等. 高效液相色谱法测定绝缘油中糠醛含量的不确定度评定[J]. 计量学报, 2022, 43(4): 560-564.
|
[28] |
JJF 1059.1—2012 测量不确定度评定与表示 [S].
|
|
Luo C P, Gan L B, Zhou Y F, et al. Simultaneous Quantitative Determination of C_(60) and C_(70) by UV/Visible Absorption Spectra[J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 1995, 31(4): 432-438.
|
|
[17]
|
[23] |
倪育才. 实用测量不确定度评定 [M]. 北京:中国计量出版社, 2004.
|
[25] |
JJG 196—2006 常用玻璃量器检定规程 [S].
|
|
Di Z, Jia B Y, Zhou L, et al. Uncertainty Evaluation for Determination of Octocrilene Derivatives as Sunscreen Agent in Cosmetics by High Performance Liquid Chromatography[J]. Acta Metrologica Sinica, 2020, 41(12): 1570-1575.
|
|
|
|