Analysis and Characterization of Mechanical Durability of Perfluorosulfonic Acid Proton Exchange Membrane

LI Yongzhe, WANG Jingjing, DING Han, WANG Kai, SHI Xiang, WANG Li, ZOU Yecheng, LIU Xundao

Acta Metrologica Sinica ›› 2025, Vol. 46 ›› Issue (6) : 795-801.

PDF(1615 KB)
PDF(1615 KB)
Acta Metrologica Sinica ›› 2025, Vol. 46 ›› Issue (6) : 795-801. DOI: 10.3969/j.issn.1000-1158.2025.06.03

Analysis and Characterization of Mechanical Durability of Perfluorosulfonic Acid Proton Exchange Membrane

Author information +
History +

Abstract

The mechanical durability of perfluorosulfonic acid proton exchange membrane (PFSA-PEM) plays an important role in the performance, life and service reliability of proton exchange membrane fuel cell (PEMFC). The mechanical durability of homogeneous and enhanced PFSA-PEM was carried out by dry-wet cycle method, and the attenuation mechanism and influencing factors were analyze. The mechanism of enhanced material on mechanical properties, dimensional change rate and durability of PFSA-PEM was verified. The results show that the method can effectively characterize the tensile strength and elastic modulus of PFSA-PEM and give the spatial location information of the local failure point from the thermal imaging, thus, provide a strong basis for further optimizing the manufacturing process parameters and improving the mechanical durability of PFSA-PEM.

Key words

fuel cell / proton exchange membrane / perfluorosulfonic acid / mechanical durability / dry-wet cycle method

Cite this article

Download Citations
LI Yongzhe , WANG Jingjing , DING Han , et al . Analysis and Characterization of Mechanical Durability of Perfluorosulfonic Acid Proton Exchange Membrane[J]. Acta Metrologica Sinica. 2025, 46(6): 795-801 https://doi.org/10.3969/j.issn.1000-1158.2025.06.03

References

1
庄林.新型纳米结构推动燃料电池电极催化剂的发展[J].物理化学学报201632(8):1853-1853.
ZHUANG L. New Nanostructures Promote the Development of Fuel Cell Electrode Catalysts [J]. Acta Physico-Chimica Sinica201632(8): 1853-1853.
2
李忠华,杜传进,侯献军.质子交换膜燃料电池热管理研究[J].电池工业200712(2):131-134.
LI Z H DU C J HOU X J. Research on Thermal Management of Proton Exchange Membrane Fuel Cells [J]. Battery Industry200712(2): 131-134.
3
肖九梅.氢燃料电池汽车及其电池现状[J].电力电子2013(3):50-54.
XIAO J M. Hydrogen Fuel Cell Vehicles and the Current Status of Their Batteries [J]. Power Electronics2013(3): 50-54.
4
谢义淳.燃料电池用复合型质子交换膜的研究[D].广州:华南理工大学,2013.
5
钱阳.质子交换膜燃料电池金属双极板表面制备纳米晶Zr基涂层[D]. 南京:南京航空航天大学,2015.
6
陈慕欣,柳佳欣,衣秀羽.质子交换膜燃料电池的研究开发与应用[J].山东化工202049(16):95-96.
CHEN M X LIU J X YI X Y. Research, development and application of proton exchange membrane fuel cells [J]. Shandong Chemical Industry201949(16):95-96.
7
章俊良,程明,罗夏爽,等.车用燃料电池电堆关键技术研究现状[J].汽车安全与节能学报202213(1):1-28.
ZHANG J L CHENG M LUO X S, et al. Research status of Key Technologies of fuel cell stacks for vehicles [J]. Journal of Automobile Safety and Energy Efficiency202213(1):1-28.
8
赵鑫,杨沄芃,郭建强.燃料电池质子交换膜研究现状与展望[J].电池工业202327(4):205-209.
ZHAO X YANG Y P GUO J Q. Research status and prospect of proton exchange membranes for fuel cells [J]. Battery Industry202327(4):205-209.
9
MOJANTA P K RIPA M S REGNET F, et al. Impact of membrane types and catalyst layers composition on performance of polymer electrolyte membrane fuel cells [J]. ChemistryOpen20209(5): 607-615
10
HUANG H, NIA L, XU S, et al. Novel proton exchange membrane with long-range acid–base-pair proton transfer pathways based on functionalized polyethyleneimine[J]. ACS Sustainable Chemistry & Engineering20219(10): 3963-3974.
11
BOSE S KUILA T NGUYEN T X H, et al. Polymer membranes for high temperature proton exchange membrane fuel cell: Recent advances and challenges [J]. Progress in Polymer Science201136(6): 813-843.
12
JIAO K XUAN J DU Q, et al. Designing the next generation of proton-exchange membrane fuel cells [J]. Nature2021595(7867): 361-369.
13
VASU G SREENIVASULU B SARMA G V S, et al. Effect of Humidifier Temperatures on Nafion-XL Membrane Electrode Assemblies (MEA)–An Experimental Study[J]. Materials Today Proceedings20185(1):765-771.
14
TAUFIQ MUSA M SHAARI N KAMARUDIN S K. Carbon nanotube, graphene oxide and montmorillonite as conductive fillers in polymer electrolyte membrane for fuel cell: an overview[J]. International Journal of Energy Research202145(2): 1309-1346.
15
梁铣,吴亮,杨正金,等.聚电解质燃料电池中的质子交换膜研究进展[J].科学通报202267(19):2226-2240.
LIANG X WU L YANG Z J, et al. Research progress of proton exchange membranes in polyelectrolyte fuel cells [J]. Chinese Science Bulletin20267(19):2226-2240.
16
INABA M KINUMOTO T KIRIAKE M, et al. Gas crossover and membrane degradation in polymer electrolyte fuel cells[J]. Electrochimica Acta200651(26): 5746-5753.
17
LYKINS C D MALL S JAIN V. An evaluation of parameters for predicting fretting fatigue crack initiation [J]. International Journal of Fatigue200022(8): 703-716.
18
ALAVIJEH A S VENKATESAN S V KJORASANY R M H, et al. Ex-situ tensile fatigue-creep testing: a powerful tool to simulate in-situ mechanical degradation in fuel cells [J]. Journal of Power Sources2016312: 123-127.
19
KHORASANY R M H ALAVIJEH A S KJEANG E, et al. Mechanical degradation of fuel cell membranes under fatigue fracture tests [J]. Journal of Power Sources2015274: 1208-1216.
20
PANHA K FOWLER M YUAN X Z, et al. Accelerated durability testing via reactants relative humidity cycling on PEM fuel cells[J]. Applied Energy201293: 90-97
21
AINDOW T T O’NEILL J. Use of mechanical tests to predict durability of polymer fuel cell membranes under humidity cycling [J]. Journal of Power Sources2011196(8): 3851-3854.
22
张茹,周斌,陈溢.全氟质子交换膜在燃料电池中的寿命测试与性能研究[J].膜科学与技术202444(4):105-114.
ZHANG R ZHOU B CHEN Y. Study on lifetime and performance of perfluorinated proton exchange membranes in fuel cells [J]. Membrane Science and Technology201944(4):105-114.
23
梁潇,许思传.车用燃料电池耐久性的研究进展[J].中国科技博览2012(3):36-38.
LIANG X XU S C. Research Progress on Durability of Automotive Fuel Cells [J]. China Science and Technology Expo2012(3):36-38.
24
周伟,何华东. 浅谈质子交换膜燃料电池耐久性的研究现状[J]. 科技信息2010(26):522-523.
ZHOU W HE H D. Research Status of proton exchange membrane fuel cell durability [J]. Science and Technology Information2010(26):522-523.
25
LIN Q YAO Y CHEN G, et al. Characterization of biaxial fatigue durability for fuel cell membranes using pressure-loaded blisters [J]. Polymer Testing2023125: 108127-108136.
26
EL‑KHAROUF A CHANDAN A HATTENBERGER M, et al. Proton exchange membrane fuel cell degradation and testing [J]. Journal of the Energy Institute201285(4): 188-200.
27
XING Y LI H AVGOUROPOULOS G. Research progress of proton exchange membrane failure and mitigation strategies [J]. Materials202114(10): 2591-2607.
28
KHORASANY R M H KJEANG E WANG G G, et al. Simulation of ionomer membrane fatigue under mechanical and hygrothermal loading conditions [J]. Journal of Power Sources2015279: 55-63.
PDF(1615 KB)

Accesses

Citation

Detail

Sections
Recommended

/