基于三维荧光与BLLS/RBL同时检测蜂蜜中3种喹诺酮类抗生素

doi:10.3969/j.issn.1000-1158.2021.09.22

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Abstract Three kinds of quinolones (fluoroquinoline, enrofloxacin and levofloxacin) in honey were analyzed by three-dimensional fluorescence spectroscopy. The spectra were pretreated to eliminate the second-order Rayleigh scattering and Raman scattering, and the spectral noise was eliminated by wavelet optimization set ensemble empirical mode decomposition (EEMD). The bilinear least square/residual bilinear (BLLS/RBL) algorithm was used to detect the samples before and after pretreatment. The results show that after pretreatment, the spectrum of each component in the sample can be accurately resolved, and it has a high similarity with the original spectrum. In the quantitative analysis, the predicted average recovery (RA) of fluoroquinoline, enrofloxacin and levofloxacin is 94.99%, 100.20%, 103.20% respectively, the root mean square error (RMSE) is 4.03, 0.21, 0.29μg/L respectively, the sensitivity (SL) is 3.2×10³, 3.5×10⁴, 3.3×10⁴μg/L, respectively; and the detection lower limit (Lout) is 2.08, 0.18, 0.19μg/L respectively, which are superior to the results without pretreatment.

Key words： metrology antibiotic residue testing BLLS/RBL wavelet optimization EEMD quinolones honey quality

Received: 17 December 2019 Published: 24 September 2021

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TB99

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	Articles by authors
	ZHAO Xing-tao
	CHE Xian-ge
	WANG Shu-tao
	LIU Shi-yu
	YUAN Yuan-yuan

Cite this article:

ZHAO Xing-tao,CHE Xian-ge,WANG Shu-tao, et al. Simultaneous Detection of Three Quinolones in Honey Based on Three-dimensional Fluorescence and BLLS/RBL[J]. Acta Metrologica Sinica, 2021, 42(9): 1257-1264.

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http://jlxb.china-csm.org:81/Jwk_jlxb/EN/10.3969/j.issn.1000-1158.2021.09.22 OR http://jlxb.china-csm.org:81/Jwk_jlxb/EN/Y2021/V42/I9/1257

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