Abstract:The certified reference material (CRM) of calorific value of isooctane is determined by the national standard of calorific value of solid fuels, an isothermal oxygen bomb calorimeter calibrated by the electric energy.The calorific value of the isooctane CRM traces to international system units including temperature, electric current, time and mass via the calibration of electric energy.The systematic errors of mass measurements and uncompleted combustion due to the volatilization of isooctane are avoided by the home-made capsule of polyethylene for the liquid sample.The gross heat of combustion of the isooctane CRM at the standard condition is 47777 J/g with an expanded uncertainty of 52 J/g (the expanded factor k=2).
王海峰, 李佳, 孙国华, 马康, 富坤, 刘军枫. 异辛烷热值标准物质[J]. 计量学报, 2013, 34(5): 502-507.
WANG Hai-feng, LI Jia, SUN Guo-hua, MA Kang, FU Kun, LIU Jun-feng. Certified Reference Material of Calorific Value of Isooctane. Acta Metrologica Sinica, 2013, 34(5): 502-507.
[1] DIN 51900—2003, Determination the gross calorific value of solid and liquid fuels using the isoperibol or static-jacket calorimeter, and calculation of net calorific value [S].
[2] ASTM 4809—2005, Standard test method for heat of combustion of liquid hydrocarbon fuels by oxygen bomb calorimeter (precision method) [S].
[3] ASTM 240—2002, Standard test method for heat of combustion of liquid hydrocarbon fuels by bomb calorimeter [S].
[4] GB/T 384—1981,石油产品热值测定法[S].
[5] Jessup S R. Precise measurement of heat of combustion with a bomb calorimeter [R]. NBS Monograph 7, 1960.
[6] 孟凡敏,孙国华,李佳. 国家燃烧热基准技术改造研究报告[R]. 中国计量科学研究院,2006.
[7] Astin A V. Certificate of standard sample 217b [R].National Bureau of Standards of USA,217b,1962.
[8] Jaeschke M, Schmücker A, Pramann A,et al.GERG Project: Development and setup of a new combustion reference calorimeter for natural gases [J].International Journal of Thermophysics, 2007, 28(1): 220-244.
[9] 孟凡敏,孙国华,吴开成.氧弹热量计热容量校准的不确定度分析[J]. 煤质技术,2004,(1): 64-66.