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计量学报  2023, Vol. 44 Issue (2): 284-289    DOI: 10.3969/j.issn.1000-1158.2023.02.19
  电离辐射、标准物质与生物计量 本期目录 | 过刊浏览 | 高级检索 |
基于协相关性和傅里叶变换-差分吸收光谱法的臭氧浓度在线测量研究
郑海明1,2,姚鹏辉3
1.广东海洋大学 机械与能源工程学院,广东阳江529500
2.华北电力大学 能源动力与机械工程学院,河北保定071003
3.河北省机电一体化中试基地,河北石家庄050000)
Research of On-line Monitoring of Ozone Concentration Based on Association Correlation and Differential Optical Absorption Spectroscopy-Fourier Transform
ZHENG Hai-ming1,2,YAO Peng-hui3
1. School of Mechanical and Energy Engineering, Guangdong Ocean University, Yangjiang, Guangdong 529500, China
2. School of Energy Power and Mechanical Engineering, North China Electric Power University, Baoding, Hebei 071003,China
3. Hebei Mechatronics Intermediate Pilot Production Base, Shijiazhuang, Hebei  050000, China
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摘要 采用协相关性和傅里叶变换-差分吸收光谱法对臭氧浓度进行了在线测量研究。先创建1套能够用于实验室在线监测臭氧浓度的发生装置,其测量精度可达到0.1×10-6;然后应用协相关性对测得的多组背景谱和吸收谱进行分析与计算,得到最优背景谱和吸收谱,进而准确反演臭氧吸收截面,优化臭氧浓度的计算过程;最后采用傅里叶变换-差分吸收光谱法以及逆傅里叶变换法在320~350nm波段反演臭氧浓度,成功消除系统噪声的干扰,得到反演臭氧浓度的二次方程。
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郑海明
姚鹏辉
关键词 计量学;臭氧浓度;差分吸收光谱法;傅里叶变换协相关性在线测量    
Abstract:The on-line measurement of ozone concentration was carried out by co-correlation and Fourier transform differential absorption spectroscopy. First, a set of generator that can be used for on-line monitoring of ozone concentration in the laboratory was created, and its measurement accuracy can reach 0.1×10-6. Then, the best background spectrum and absorption spectrum can be obtained by calculating the measured multi group background spectrum and absorption spectrum by using the co correlation, so as to accurately retrieve the ozone absorption cross section and optimize the calculation process of ozone concentration. Finally, Fourier transform differential absorption spectroscopy and inverse Fourier transform were used to retrieve ozone concentration in 320~350nm band, the interference of system noise was successfully eliminated and the quadratic equation for retrieving ozone concentration was obtained.
Key wordsmetrology    ozone concentration    differential absorption spectroscopy    Fourier transform    association correlation    on-line monitoring
收稿日期: 2021-03-19      发布日期: 2023-02-21
PACS:  TB99  
基金资助:国家自然科学基金(11174078);河北省自然科学基金(E2019502089);中央高校基本科研业务费专项资金(2017MS145)
作者简介: 郑海明(1972-),男,江西乐安人,华北电力大学教授,博士,主要从事污染源烟气烟尘连续在线计量检测、光机电技术应用等方向的研究。Email: haimingzheng@163.com
引用本文:   
郑海明,姚鹏辉. 基于协相关性和傅里叶变换-差分吸收光谱法的臭氧浓度在线测量研究[J]. 计量学报, 2023, 44(2): 284-289.
ZHENG Hai-ming,YAO Peng-hui. Research of On-line Monitoring of Ozone Concentration Based on Association Correlation and Differential Optical Absorption Spectroscopy-Fourier Transform. Acta Metrologica Sinica, 2023, 44(2): 284-289.
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