Abstract:In order to solve the problem that SO2 fluorescence signals was faint and always cannot be distinguished with noises, a novel method based on wavelet optimization ensemble empirical mode decomposition (EEMD) was proposed. The SO2 detection system had been built. Using the SO2 detection system, SO2 concentration can be detected. The average error of detection was 0.0011, and the correlation coefficients between SO2 concentration and the fluorescence intensity was 0.9787. Wavelet optimization EEMD denoising method were applied to SO2 detection system, the results showed that the signal noise ratio(SNR) was 224.7958, the mean squared error(MSE) was 1.01×10-7, and the normalized correlation coefficient(NCC) was 0.9973. The correlation coefficients between SO2 concentration and fluorescence intensity was 0.9936. Compared with the wavelet denoising method and EEMD denoising method, the wavelet optimization EEMD method has the best denoising effect. The proposed method is superior to wavelet denoising method and EEMD denoising method.
[1]Solomon P A, Wexler A S, Sioutas C. Special Issue of Atmospheric Environment for Air Pollution and Health: Bridging the Gap from Sources-to-Health Outcomes Preface[J]. Atmospheric Environment, 2011, 45(40): 7537-7539.
[2]Yu Y J, Yu Z L, Sun P, et al. Effects of ambient air pollution from municipal solid waste landfill on childrens non-specific immunity and respiratory health[J]. Environmental Pollution, 2018, 236: 382-390.
[3]Zhao Y, Duan L, Xing J, et al. Soil acidification in China: Is Controlling SO2 Emissions Enough[J]. Environmental Science & Technology, 2009, 43(21): 8021-8026.
[4]张大伟. 刍议大气污染及其防治措施[J]. 环境与发展, 2017, 29(10): 104-105.
Zhang D W. Discussion on air pollution and its control measures[J]. Environment and Development, 2017, 29(10): 104-105.
[5]GB3095—2012 环境空气质量标准[S].
[6]孙利群, 陈克新, 杨怀栋, 等. 基于差分吸收光谱法的大气痕量气体在线检测技术[J]. 应用光学, 2012, 33(1): 115-119.
Sun L Q, Chen K X, Yang H D, et al. On-line monitoring technique for trace gases in atmosphere based on differential optical absorption spectroscopy[J]. Journal of Applied Optics, 2012, 33(1): 115-119.
[7]Liu Y Y, Xu X Y, Hen Y, et al. An Integrated Micro-chip with Ru/Al2O3 /ZnO as Sensing Material for SO2 Detection[J]. Sensors & Actuators B Chemical, 2018, 262: 26-34.
[8]王玉田, 王宴婷. 基于小波变换的荧光检测信号的去噪研究[J]. 计量与测试技术, 2009, 36(1): 1-2+5.
Wang Y T, Wang Y T. Research on de-noising of fluorescence detecting signal based on wavelet transform[J]. Metrology & Measurement Technique, 2009, 36(1): 1-2+5.
[9]王书涛, 李梅梅, 李盼, 等. 基于经验模态分解的SO2浓度检测信号处理方法[J]. 光子学报, 2014, 43(2): 14-19.
Wang S T, Li M M, Li P, et al. Signal processing method based on empirical mode decomposition in the SO2 concentration monitoring[J]. Acta Photonica Sinica, 2014, 43(2): 14-19.
[10]王玉田, 监雄, 王惠新, 等. 基于Boxcar滤波器的荧光检测二氧化硫信号的去噪研究[J]. 光谱学与光谱分析, 2012, 32(12): 3285-3289.
Wang Y T, Jian X, Wang H X, et al. Research on denoising fluorescence signal of sulfur dioxide by Boxcar filter[J]. Spectroscopy and Spectral Analysis, 2012, 32(12): 3285-3289.
[11]Huang N E, Shen Z, Long S R,et al. The empirical mode decomposition and the Hilbert spectrum for nonlinear and non-stationary time series analysis[J]. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 1998, 454(1971): 903-955.
[12]Wu Z H, Huang N E. Ensemble Empirical Mode Decomposition: A noise Assisted Data Analysis Method[J]. Advances in Adaptive Data Analysis, 2009, 1(1): 1-41.
[13]朱江淼,闫迪,高源, 等. 基于改进EEMD和LSSVM的单频周跳探测与修复方法[J]. 计量学报, 2019, 40(3): 491-497.
Zhu J M, Yan D, Gao Y, et al. The Method for Single-frequency Cycle-slip Detection and Reparation Based on Modified EEMD and LSSVM[J].Acta Metrologica Sinica, 2019, 40(3): 491-497.
[14]张淑清,乔永静,姜安琦,等. 基于CEEMD和GG聚类的电能质量扰动识别[J]. 计量学报, 2019, 40(1): 49-57.
Zhang S Q, Qiao Y J, Jiang A Q,et al. Power Quality Disturbance Identification Based on CEEMD and GG Clustering[J]. Acta Metrologica Sinica, 2019, 40(1): 49-57.
[15]宋萌萌, 肖顺根, 陈肇祥. 基于提升小波变换与EEMD的神经网络齿轮故障诊断方法[J]. 组合机床与自动化加工技术, 2017,(9): 93-98.
Song M M, Xiao S G, Chen Z X. Neural network fault diagnosis method of gear based on EEMD and lifting wavelet transform[J]. Modular Machine Tool & Automatic Manufacturing Technique, 2017,(9): 93-98.
[16]赵肖宇. 基于EMD和EEMD的自适应光谱预处理方法及其应用研究[D]. 秦皇岛: 燕山大学, 2015.
[17]王天伟, 张厚江, 路敦民, 等. 基于小波去噪和经验模态分解算法的足尺人造板动态称重研究[J]. 计量学报, 2017, 38(3): 300-303.
Wang T W, Zhang H J, Lu D M, et al. Dynamic weighing of full-size wood composite panels based on wavelet denoising and empirical mode decomposition algorithm[J]. Acta Metrologica Sinica, 2017, 38(3): 300-303.
[18]Donoho D L. De-noising by soft-thresholding[J]. IEEE Transactions on Information Theory, 2002, 41(3): 613-627.