石墨烯及其复合材料导热系数测量的研究进展

周逸; 林鸿; 冯晓娟; 邱萍; 佘世刚; 张金涛

doi:10.3969/j.issn.1000-1158.2020.02.06

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计量学报 ›› 2020, Vol. 41 ›› Issue (2) : 159-169. DOI: 10.3969/j.issn.1000-1158.2020.02.06

热学计量

石墨烯及其复合材料导热系数测量的研究进展

周逸^1,2,3,林鸿²,冯晓娟²,邱萍²,佘世刚¹,张金涛²

作者信息 +

Research the Progresses on Measurement of Thermal Conductivity of Graphene and Graphenes Composites

ZHOU Yi^1,2,3,LIN Hong²,FENG Xiao-juan²,QIU Ping²,SHE Shi-gang¹,ZHANG Jin-tao²

Author information +

文章历史 +

摘要

石墨烯是当下材料学研究的热点和难点,其优越的导热性能,超越了绝大多数的材料,具有广泛的运用前景。近10年来,石墨烯产业的快速发展对其导热系数准确测量的需求越来越迫切。对石墨烯及其复合材料的定义、制备方法和在散热上的应用进行了综述;介绍了传统的导热系数测量方法,以及适用于石墨烯导热系数测量的激光闪光-拉曼光谱法和电热微桥法,对比了部分文献报道的石墨烯导热系数测量值;对熔融注塑法制备的还原氧化石墨烯和聚丙烯复合材料样品的导热系数和热扩散系数进行了测量,从热扩散系数测量结果发现其导热性能存在严重的各向异性;根据测量研究进展指出当前石墨烯及其复合材料导热系数测量存在的问题,并分析了导致这些问题的原因;最后,对石墨烯及其复合材料导热系数测量的研究进展进行总结和展望。

Abstract

Graphene, which has thermal conductivity surpasses most materials and broad application prospects, is a hot and difficult topic in current material research. Over the past decade, due to the rapid development of graphene industry, the accurate measurement of graphenes thermal conductivity is becoming more and more urgent. Definitions, preparation methods of graphene and graphenes composites and application in heat dissipation are reviewed. Traditional measurement methods of thermal conductivity, the laser flash-Raman spectroscopy method and electrothermal microbridge method for graphene are introduced. The measured values reported in some existing literatures are also compared. Prepared and measured samples which compounded of reduced graphene oxide and polypropylene by injection moulding, then find serious anisotropy form the measurement results of thermal diffusivity. Also, other problems in the measurement are pointed out and the causes of these problems are analyzed. Finally, summarize and prospect the measurement research on thermal conductivity of graphene and graphene‘s composites.

导出引用

周逸,林鸿,冯晓娟,邱萍,佘世刚,张金涛. 石墨烯及其复合材料导热系数测量的研究进展[J]. 计量学报. 2020, 41(2): 159-169 https://doi.org/10.3969/j.issn.1000-1158.2020.02.06

ZHOU Yi,LIN Hong,FENG Xiao-juan,QIU Ping,SHE Shi-gang,ZHANG Jin-tao. Research the Progresses on Measurement of Thermal Conductivity of Graphene and Graphenes Composites[J]. Acta Metrologica Sinica. 2020, 41(2): 159-169 https://doi.org/10.3969/j.issn.1000-1158.2020.02.06

中图分类号： TB941

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